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Methyl 4-(bromomethyl)benzoate

Methyl 4-(bromomethyl)benzoate

CAS: 2417-72-3

Molecular Formula: C9H9BrO2

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Methyl 4-(bromomethyl)benzoate - Names and Identifiers

Name Methyl 4-(bromomethyl)benzoate
Synonyms 4-bromomethyl benzoate
Methyl 4-broMoMethylbenzoato
METHYL ALPHA-BROMO-P-TOLUATE
Methyl 4-(bromomethyl)benzoate
METHYL P-(BROMOMETHYL)BENZOATE
Methyl-4-[Bromomethyl]Benzoate
p-(Methoxycarbonyl)benzyl bromide
ALPHA-BROMO-P-TOLUIC ACID METHYL ESTER
4-Bromomethyl benzoic acid methyl ester
4-(BROMOMETHYL)BENZOIC ACID METHYL ESTER
4 - broMine Methyl benzoic acid Methyl ester
Benzoic acid, 4-(bromomethyl)-, methyl ester
CAS 2417-72-3
EINECS 607-335-7
InChI InChI=1/C9H9BrO2/c1-12-9(11)8-4-2-7(6-10)3-5-8/h2-5H,6H2,1H3

Methyl 4-(bromomethyl)benzoate - Physico-chemical Properties

Molecular FormulaC9H9BrO2
Molar Mass229.07
Density1,47 g/cm3
Melting Point57-58°C(lit.)
Boling Point130-135°C2mm Hg(lit.)
Flash Point130-135°C/2mm
Water SolubilityLowly soluble in water, highly soluble in ethanol and ether, not soluble in halogenated organic solvents
Vapor Presure0.00063mmHg at 25°C
AppearanceCrystalline Powder, Crystals and/or Chunks
ColorWhite to yellow
BRN1867272
Storage Conditionunder inert gas (nitrogen or Argon) at 2-8°C
SensitiveLachrymatory
Refractive Index1.5320 (estimate)

Methyl 4-(bromomethyl)benzoate - Risk and Safety

Hazard SymbolsC - Corrosive
Corrosive
Risk CodesR22 - Harmful if swallowed
R34 - Causes burns
R43 - May cause sensitization by skin contact
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S25 - Avoid contact with eyes.
UN IDsUN 3261 8/PG 2
WGK Germany3
HS Code29163990
Hazard NoteIrritant
Hazard Class8
Packing GroupIII

Methyl 4-(bromomethyl)benzoate - Reference Information

introduction methyl 4-bromomethylbenzoate is an organic intermediate, which can be prepared from p-methylbenzoic acid through two routes. p-methylbenzoic acid can be first esterified to prepare methyl p-methylbenzoate, and then brominated to obtain methyl 4-bromomethylbenzoate or from p-methylbenzoic acid first brominated to obtain p-bromomethylbenzoic acid, and then esterified to obtain methyl 4-bromomethylbenzoate.
Last Update:2024-04-09 15:16:45
Methyl 4-(bromomethyl)benzoate
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View History
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